Additives for polyamides and polyesters

Additives for recycling of polyolefins

Plastics that must meet high require­ments need support: Under the trade name BRUG­GOLEN® we offer special high-perform­ance addit­ives for tech­nical plastics with an emphasis on poly­amide (PA 6, PA 6.6, PA 12, and copoly­amide), including heat, processing, and light stabil­izers, processing aids, and modi­fiers. BRUG­GOLEN® polymer addit­ives can be used in injec­tion molding and extru­sion, as well as in the pack­aging industry and fiber industry. These polymer addit­ives ensure effi­cient processing as well as an improved service life for plastic parts, and they offer high quality on econom­ical terms. Our polymer addit­ives are readily avail­able as indi­vidual products or combin­a­tion products (One-Packs). One-Packs are ready-mixed compounds of two or more addit­ives and they are tailored to special solu­tions and applic­a­tions. One-Packs are avail­able as powder, compactate, or master batch, and in this regard help to save almost half of the additive raw mater­ials.

Heat Stabil­izers

For many mater­ials the phys­ical prop­er­ties and the appear­ance of the plastic are in some cases consid­er­ably changed through the influ­ence of heat, light, and atmo­spheric oxygen. In this regard a distinc­tion is made between processing stabil­izers that primarily coun­teract polymer degrad­a­tion in the melt phase (compounding, injec­tion molding, extru­sion), long-term stabil­izers that prevent polymer degrad­a­tion under increased ambient temper­at­ures (60 - 130°C) during finished part use, high-temper­ature stabil­izers that are effective up to 180°C, and UV stabil­izers for effective protec­tion of finished parts against polymer degrad­a­tion by through UV radi­ation. Combin­a­tions of different addit­ives provide addi­tional synergy effects.

Copper-salt-based anti-oxid­ants:
Highly effi­cient heat stabil­iz­a­tion of poly­amides up to 180°C

Classic heat stabil­izers based on copper salts
BRUG­GOLEN® H320 / H321*

BRUG­GOLEN® H324 / H325*

BRUG­GOLEN® H328F / H329F*

Powerful long-term protec­tion

  • Char­ac­ter­istic bluish or greenish color after condi­tioning
  • Excel­lent quality and homo­­gen­eity via specific produc­­tion know-how
  • Variety of stabil­­izers to serve all customer require­ments
New Copper Iodide Based Heat Stabil­izer (up to 180°C) 
BRUG­GOLEN® TP-H1607*

Prolongs reten­tion of mech­an­ical prop­er­ties compared to classic copper stabil­izers

  • high effi­ciency enables low dosage
  • broad applic­a­tion including E&E (allows high CTI of 600V)
  • new, propri­etary tech­no­logy
  • more compet­itive solu­tion than CuI/KI stabil­izers
  • excel­lent disper­sion, easy hand­ling, accurate dosing
Copper-complex-based heat stabil­izers for reten­tion of the natural poly­amide color after condi­tioning
BRUG­GOLEN® H3386 / H3387*

BRUG­GOLEN® H3350 / H3351**

Powerful long-term stabil­­iz­a­­tion / natural colors

  • Excel­lent UV stabil­iz­a­tion
  • Very effective disper­sion
  • H3351** Master­batch is suit­able for mono­fil­a­ment and fiber applic­a­tions
BRUG­GOLEN® H3376 / H3377*

Espe­cially suited for applic­a­tions in the elec­trical/elec­tronics sector

  • High compar­ative tracking index (CTI) up to 600 V
  • H3377* compacted gran­u­late is suit­able for mono­fil­a­ment and fiber applic­a­tions
  • High extrac­­tion resist­ance; no plate-out
Copper-complex-based heat stabil­izers with char­ac­ter­istic bluish discol­or­a­tion after condi­tioning
BRUG­GOLEN® H3336 / H3346*

BRUG­GOLEN® H3344 / H3345*
  • Cost-effective
  • Excel­lent disper­sion
  • High extrac­­tion resist­ance; no plate-out
  • H3345* compacted gran­u­late is suit­able for mono­fil­a­ment and fiber applic­a­tions
  • suit­ed for E&E applic­a­­tions
High Heat Stabil­izer for Aliphatic Poly­amides above 200°C 
BRUG­GOLEN® TP-H1805**

Powerful long-term protec­tion of aliphatic poly­amides at very high temper­at­ures: PA6 up to 200°C, PA6.6 up to 230°C

  • tensile strength reten­tion >50% for 3000 h at 200°C
  • no activ­a­tion required
  • easy processing during compounding
  • upgrades aliphatic poly­amides to the perform­ance range of high temper­ature nylons

All products in powder form, except *Poly­meric Gran­u­late **Master­batch

BRUG­GOLEN H: heat stabil­izers for poly­amides

Process stabil­izers
BRUG­GOLEN® H10

Best protec­tion of poly­amides against discol­or­a­­tion during processing

  • reduced yellowing during melt processing
  • protec­tion against discol­or­a­­tion after ageing by heat and by UV light
  • H10 is superior to organic phos­phites because of its:
  • excel­lent resist­ance against high shear stress and elev­ated temper­­at­ures
  • non-volat­ility
  • resist­ance against hydro­lysis
  • Espe­­cially suited for  glass-fiber rein­­forced poly­­­am­ides
Phenol-based stabil­izers
BRUG­GOLEN® H164

Long-term protec­­tion of poly­amides against heat aging for tech­n­ical applic­a­­tions

  • Non-discol­ouring
  • excel­lent in glass fiber rein­­forced or mineral-filled poly­­­am­ides
BRUG­GOLEN® H161

Long-term protec­­tion of poly­amide fibres and unfilled injec­­tion/extru­sion grades

  • Excel­lent color stabil­­iz­a­­tion, e.g., during storage
  • Non-extract­­able, no plate-out
BRUG­GOLEN® H175

Extremely effi­cient color stabil­iz­a­tion and long-term heat stabil­iz­a­tion of tech­nical plastics

  • Non-extract­­able, no plate-out
  • Also effective in poly­es­ters, polycar­bon­ates and styrene poly­mers
  • Excel­lent color stabil­iz­a­tion
BRUG­GOLEN® H180

Excel­lent processing stabil­­izer and anti­­ox­idant package for poly­­acetals

  • scav­enges form­al­de­hyde
Phen­olic Plus: Phen­olic based Heat Stabil­izer Package with Extended Temper­ature Range
BRUG­GOLEN® TP-H1803*

Outper­forms conven­tional phen­olic based stabil­izers

  • improved reten­tion of mech­an­ical perform­ance under heat
  • extended heat stabil­iz­a­tion for short-term peak temper­ature of up to 180°C
  • phen­olic stabil­izer package upgraded with copper complex tech­no­logy (low copper content)
Copper- and halogen-free heat stabil­izer for poly­amides in E&E applic­a­tions
BRUG­GOLEN® TP-H2062***
  • improved reten­­tion of mech­an­ical perform­ance under heat compared to standard phos­phite/phen­olic based stabil­izers
  • tensile strength reten­tion >50% for 2500h at 150°C
  • main­tains compar­ative tracking index (CTI) up to 600V
  • allows E&E applic­a­tions at elev­ated temper­at­ures
  • halogen and metal-free heat stabil­izer in gran­ular product form
Amine-based stabil­izers
BRUG­GOLEN® TP-H1802

Protec­tion of poly­amides against hot oils, fats and glycols

  • Good long-term stabil­­iz­a­­tion
  • Char­ac­ter­­istic brownish-trans­lu­­cent discol­or­a­­tion
  • not CMR clas­si­fied, free of DPPD

Processing Agents for poly­amides and poly­es­ters

With its processing agents, Brügge­mann supports poly­amide compounders in cost-effi­ciently improving the processing char­ac­ter­istics of poly­amides. In this way, the flow­ab­ility of poly­amides rein­forced with glass fiber, for example, can be increased and their good mech­an­ical prop­er­ties can be retained. Such highly-satur­ated poly­amides are an outstanding replace­ment for metal in tech­nical parts.

Nucle­ating agents
BRUG­GOLEN® P22
For poly­amides

BRUG­GOLEN® P252
For poly­es­ters

Highly-effi­cient nucle­ating agent for poly­amides (P22) and poly­es­ters (P252)

  • reduc­tion of cycle time during injec­tion molding
  • improved dimen­sional stability - signi­ficant reduc­tion of warping in GD-rein­forced compounds
  • Improves mech­an­ical prop­er­­ties (tensile strength, stiff­ness, etc.)
  • Increases heat distor­tion temper­­ature
  • Non-volatile; non-extract­­able
BRUG­GOLEN® TP-P1401**

Nucle­­ating agent for poly­­­am­ides – in gran­u­late form

  • suited for higher processing temper­at­ures
  • easy to dose, disperse and process
  • improved surface prop­er­ties of nucle­ated compounds
  • For applic­a­tions in compounding and directly infor applic­a­tion both in compounding and injec­tion molding injec­tion molding
Flow improver for poly­amides

BRUG­GOLEN® P1507**

 

BRUG­GOLEN® TP-P1810**

Improved flow and outstanding mech­an­ical prop­er­ties

  • Outstanding melt flow; signi­fic­antly longer spiral-flow filling
  • No influ­ence on mech­an­ical prop­er­ties (modulus of elasti­city, tensile strength, elong­a­tion, impact strength is retained)
  • Better process­ab­ility of glass-fiber-rein­forced poly­amides
  • Offers advant­ages for injec­tion-mold processing, such as shorter cycle times, lower energy consump­tion, use of highly complex part designs
  • Easy to dose and disperse
Processing Agents
BRUG­GOLEN® P14 
for Poly­amides

BRUG­GOLEN® P130 
for Poly­amides and Poly­es­ters

Combin­a­tion of internal and external lubric­ants

  • very effi­cient due to minimal volat­ility and high temper­ature stability
  • high-gloss and good surface protec­tion
  • excel­lent mold release
  • broadened processing window
Processing One-Packs for Poly­amides (Prime Grades/Recyc­lates) 
BRUG­GOLEN® P30 / P31**

BRUG­GOLEN® P32 / P33**

Ready-to-use, syner­­­gistic combin­a­­tions for injec­­tion moulding 

  • P30/P31* is specific­ally suited for recyc­ling of fiber waste or regrind
  • improved melt flow
  • effi­cient color protec­tion / processing stabil­iz­a­tion
Processing Auxil­iary (liquid) for Dry Blending
BRUG­GOLEN® P60

Improved quality of dry blends (polymer gran­u­late + powder additive)

  • Reduces separ­a­tion during trans­port
  • Improves disper­sion of addit­ives
All products in powder form, except ** Polymer Gran­u­late

Modi­fiers

Brügge­mann offers modi­fiers, for both chain build-up and chain disin­teg­ra­tion. For example, with its “chain shortener” the molecular weight of highly viscous poly­amide wastes can be trans­formed into high-perform­ance injec­tion molding types, whose mech­an­ical prop­er­ties corres­pond to those of on off-the-shelf new injec­tion molded type of the same viscosity. Cost advant­ages included.

Chain extenders for poly­amides
BRUG­GOLEN® M1251 **

BRUG­GOLEN® M1253**

Unique increase of molecular weight via linear chain exten­­sion

  • No cross-linking
  • Upgrade from injec­tion molding quality to extru­sion quality
  • Increase of impact strength
  • Increased elong­a­tion at break
  • typical applic­a­­tions in extru­­sion, blow-molding, recyc­ling, and injec­­tion moulding
  • M1253 micro-gran­u­late suit­able for mono­fil­a­ments and fiber applic­a­tions
Chain Breaking Agent for the recyc­ling of High Viscous Poly­­­amide Waste
BRUG­GOLEN® M1417**

Controlled and repro­du­cible reduc­tion of molecular weight

  • Exact adjust­­ment of the relative viscosity to specified target values
  • Upcyc­ling to injec­­tion molding grades
  • Gener­ating flow prop­er­ties and mech­an­ical perform­ance compar­able to that of prime material
  • Allowing cost advant­ages through usab­ility of scrap and waste mater­i­aldue to reuse of waste material
  • enabling recyc­ling of cast nylon waste
All products in polymer gran­u­late form

Light stabil­izers

Strength­ening and bright­ening: Brügge­mann’s light stabil­izers provide compounders with addit­ives that specific­ally improve the color stability of poly­amides.

Light Stabil­izers/Optical bright­eners for Engin­eering Ther­mo­plastics
BRUG­GOLEN® L11

Very effi­­cient optical bright­ener + stabil­­izer package

  • Bright­ening of colors
  • Improving color stability via better resist­ance to high processing temper­­at­ures
  • Masking of yellow discol­or­a­tion
BRUG­GOLEN® L20

BRUG­GOLEN® L206

Effective protec­­tion against aging caused by UV light and heat

  • Syner­­­gistic UV-stabil­­iz­a­tion pack­ages
  • L20 for pigmented systems, L206 for unpig­mented systems

Recyc­ling Addit­ives for Poly­ol­efines

Brug­golen® R recyc­ling addit­ives improve the poly­ol­efin recyc­ling processes and help recyclers to produce higher value poly­ol­efine recyc­lates for long term applic­a­tions. For the first time the new repairing tech­no­logy allows to repair damages from prior use.

Recyc­ling Addit­ives for poly­ol­efins

BRUG­GOLEN® R8895

for Polypro­pylen from

battery cases

 

Upcyc­ling of Polypro­pylene from car battery cases

  • Repair of damage in the polymer chains by novel chem­ical system. 
  • High quality recyc­lates for demanding long term applic­a­tions 
  • Prolonged reten­tion of mech­an­ical prop­er­ties during long term heat aging.
  • Neut­ral­iz­a­tion of acidic contam­in­a­tions. 
  • One-Pack solu­tion stabil­izes the recyc­ling process.

BRUG­GOLEN® TP-R2090

for Polypro­pylene from

post-indus­trial and

post-consumer-streams

Upcyc­ling of post-indus­trial and post-consumer polypro­pylen waste streams

  • Repair of damage in the polymer chains by novel chem­ical system. 
  • High quality recyc­lates for demanding long term applic­a­tions 
  • Prolonged reten­tion of mech­an­ical prop­er­ties during long term heat aging.
  • One-Pack solu­tion stabil­izes the recyc­ling process

BRUG­GOLEN® TP-R2162

for Poly­ethylene from

post-indus­trial and

post-consumer-streams

Upcyc­ling of post-indus­trial and post-consumer poly­ethylen waste streams

 

  • Soon:  We will transfer our „repair tech­no­logy“ on poly­ethylene.

Product forms (as indic­ated)

fine to coarse powder                        * low dust compacted pellets                      ** dust-free poly­meric gran­ules

Contacts

Peter Beck

Senior Technical Marketing Manager Polymer Additives

Tel.: Phone: +49 71 31 15 75-182

Fax: +49 71 31 15 75-25 182

peter.beck (at) brueggemann.com

Elisabeth Bierhalter

Customer Service Polymer Additives

Tel.: Phone: +49 71 31 15 75-174

Fax: +49 71 31 15 75-25 174

elisabeth.bierhalter (at) brueggemann.com

Christian Bauer

Customer Service Polymer Additives

Tel.: Phone: +49 71 31 15 75-179

Fax: +49 71 31 15 75-25 179

christian.bauer (at) brueggemann.com